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Economic Geology News

Six Main Insights from Tsavorite Minerogenetic System Analysis (November 1, 2018)

I will be speaking at the 1st Conference of the Arabian Journal of Geosciences in the Russelior Hotel & Spa at Yasmine Hammamet, Tunisia, on November 13th between 8,30 and 10,30 h about `The tsavorite (gem quality vanadium grossular) minerogenetic system in East Africa'. If you are interested, come or drop me a line.

The main conclusions I'll present are the following:

  • Source rock composition (organic-rich and evaporitic) was critical
  • Energy input by granulite facies metamorphism at 800 plus/minus 50 degrees C and 10 plus/minus 1 kbar (Jacob et al. 2018)
  • Driven by metamorphism, sulfate and organic C reacted to form reduced sulfur phases such as S0 and S-2, or the trisulfur anion S3 minus
  • Metamorphic partial melting produced a peculiar sulfurous corrosive hydrous and overpressured supercritical fluid/melt phase
  • Lateral secretion of fluid/melt phase was limited to metres, possibly with fraction of fluids increasing with distance
  • Traps for gem crystallization were deformation-related lower-pressure fissures, opening bedding planes or pockets.
  • You may notice that I differ in several points from Jacob et al. (2018), the most recent paper on the tsavorites, but here is not the place to discuss details.

    Jacob, J.-B., Martelat, J.-E., Goncalves, P., Giuliani, G., et al. (2018) New P-T-X conditions for the formation of gem tsavorite garnet in the Voi area (southwestern Kenya). Lithos 320 to 321, 250 to 264. https://doi.org/10.1016/j.lithos.2018.09.010


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    Carbon capture, utilization, and storage (CCUS) urgently needed to decarb the green biofuel industry! (October 10, 2018)

    This is not about coal! Published in September 2018, this paper (Edwards & Celia 2018) describes how the so-called green biofuel industry may rapidly reduce its CO2 emissions in order to help keeping within the Paris climate agreement. The authors report that ethanol fermentation at biorefineries in the midwestern US is a major emission source of CO2 that could be halved by building a moderately-sized new network of CO2 pipelines. Carbon dioxide from ethanol fermentation constitutes most of the midwestern low-capture-cost emissions (35 Mt per year and 90% of the Midwest total). Edwards & Celia base their financial evaluation on substantial new tax credits passed by the US Congress in February 2018, that incentivize new CCUS projects.

    In 2017, the USA output of CO2 was ~5000 Mt (15% of the world total), slowly falling. Biofuels production was ~37 Mt (toe) and growing at 2.9% annually (BP Statistical Review of World Energy 2018) .

    Ethanol
    A typical ethanol plant in West Burlington, Iowa (Big River Resources, LLC). Photo by Steven Vaughn. Wikimedia Commons.

    .

    Read Edwards & Celia (2018) Abstract:

    Carbon capture, utilization, and storage (CCUS) is a crucial technology needed to limit warming to the 2 degrees C target of the Paris Agreement. However, deployment is lagging far behind estimates of what is required. Globally, only 31 million metric tons (Mt) per year of anthropogenic carbon dioxide are currently captured and injected into geological formations for permanent storage.

    We demonstrate an opportunity to significantly expand CCUS in the United States in the near-term, spurred by new financial incentives enacted in February 2018, by targeting the lowest-cost capture opportunities and by deploying only commercially proven technologies. The carbon dioxide pipeline transport network would serve near-term oil industry demand for carbon dioxide while also connecting multiple prospective long-term dedicated geological storage resources. This would be a flexible long-term infrastructure asset for carbon management in the United States that would enable and accelerate future CCUS deployment. In February 2018, the United States enacted significant financial incentives for carbon capture, utilization, and storage (CCUS) that will make capture from the lowest-capture-cost sources economically viable. The largest existing low-capture-cost opportunity is from ethanol fermentation at biorefineries in the Midwest. An impediment to deployment of carbon capture at ethanol biorefineries is that most are not close to enhanced oil recovery (EOR) fields or other suitable geological formations in which the carbon dioxide could be stored. Therefore, we analyze the viability of a pipeline network to transport carbon dioxide from Midwest ethanol biorefineries to the Permian Basin in Texas, which has the greatest current carbon dioxide demand for EOR and large potential for expansion. We estimate capture and transport costs and perform economic analysis for networks under three pipeline financing scenarios representing different combinations of commercial and government finance. Without government finance, we find that a network earning commercial rates of return would not be viable. With 50% government financing for pipelines, 19 million tons of carbon dioxide per year could be captured and transported profitably. Thirty million tons per year could be captured with full government pipeline financing, which would double global anthropogenic carbon capture and increase the United States carbon dioxide EOR industry by 50%. Such a development would face challenges, including coordination between governments and industries, pressing timelines, and policy uncertainties, but is not unprecedented. This represents an opportunity to considerably increase CCUS in the near-term and develop long-term transport infrastructure facilitating future growth.

    This is only one of many possible contributions of the geosphere to mitigation of CO2 emissions into the atmosphere. Why not encourage more research, innovation and development? Is yesterdays call for unprecedented changes by ICCP possibly premature?

    BP (2018) BP Statistical Review of World Energy. 49 pp. 67th ed. URL https://www.bp.com/en/global/corporate/energy-economics/statistical-review-of-world-energy.html. June 2018. Open Access.

    Edwards, R.W.J. & Celia, M.A. (2018) Infrastructure to enable deployment of carbon capture, utilization, and storage in the United States. PNAS 115, E8815-E8824. PNAS Table of Contents for September 18, 2018; Vol. 115, No. 38 E8815-E8824; published ahead of print September 4, 2018 (online I bought a PDF for 10 US $). https://doi.org/10.1073/pnas.1806504115


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    Trajectories of the Earth System in the Anthropocene (August 15, 2018)

    This is the title of a truly remarkable paper that appeared a couple of days ago. Remarkable, because of its radicality and the profuse Supporting Information. And, it can be freely downloaded from the PNAS website!

    Unfortunately at this time, I am working day and night on a project and cannot really comment on the contents. But I can say that this is great thinking and that all Earth scientists and practicians of Earth Science should be informed.

    I still hesitate to accept the term Anthropocene as a geological epoch, however, and I am critical of the authors tendency to continue with the traditional climate business although they ask much more of the same. But nevertheless, their paper is brilliant!

    Steffen, W., Rockstroem, J., Richardson, K., et al. (2018) Trajectories of the Earth System in the Anthropocene. Proc. Natl. Acad. Sci. USA 115, 8252-8259.

    Abstract

    We explore the risk that self-reinforcing feedbacks could push the Earth System toward a planetary threshold that, if crossed, could prevent stabilization of the climate at intermediate temperature rises and cause continued warming on a Hothouse Earth pathway even as human emissions are reduced. Crossing the threshold would lead to a much higher global average temperature than any interglacial in the past 1.2 million years and to sea levels significantly higher than at any time in the Holocene. We examine the evidence that such a threshold might exist and where it might be. If the threshold is crossed, the resulting trajectory would likely cause serious disruptions to ecosystems, society, and economies. Collective human action is required to steer the Earth System away from a potential threshold and stabilize it in a habitable interglacial-like state. Such action entails stewardship of the entire Earth System biosphere, climate, and societies and could include decarbonization of the global economy, enhancement of biosphere carbon sinks, behavioral changes, technological innovations, new governance arrangements, and transformed social values.

    Steffen
    Figure 2 Earth_System_Stability_(Steffen_et_al_2018)

    Subtitle of Figure 2: Stability landscape showing the pathway of the Earth System out of the Holocene and thus, out of the glacial interglacial limit cycle to its present position in the hotter Anthropocene. Currently, the Earth System is on a Hothouse Earth pathway driven by human emissions of greenhouse gases and biosphere degradation toward a planetary threshold at 2 degrees C, beyond which the system follows an essentially irreversible pathway driven by intrinsic biogeophysical feedbacks. The other pathway leads to Stabilized Earth, a pathway of Earth System stewardship guided by human-created feedbacks to a quasistable, human-maintained basin of attraction. Stability (vertical axis) is defined here as the inverse of the potential energy of the system. Systems in a highly stable state (deep valley) have low potential energy, and considerable energy is required to move them out of this stable state. Systems in an unstable state (top of a hill) have high potential energy, and they require only a little additional energy to push them off the hill and down toward a valley of lower potential energy.

    PNAS August 14, 2018. 115 (33) 8252-8259; published ahead of print August 6, 2018. https://doi.org/10.1073/pnas.1810141115


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    Mount Weld Rare Earth Element (REE) Mine, Australia (July 18, 2018)

    Lateritic blankets of regolith above carbonatite are at present often deposits of niobium (e.g. Araxa, Brazil) and/or phosphate. Most display enrichment of REE, but profitable recovery from apatite is not easy. However, production from lateritic ore with leachable REE can be profitable:

    At the volcanic Mt. Weld carbonatite plug and maar in Western Australia (2025 Ma), JORC reserves are reported as ~10 Mt at 11% REO + Y. The estimate is based on a cut-off grade of 2.5% REO (Lynas Corporation 2018). The high grades are due to supergene enrichment. Ore comprises pyrochlore, REE-rich residual apatite and secondary Th-depleted monazite disseminated in fine-grained iron oxides. REE ore minerals are concentrated by flotation to ~40% REO. Further processing takes place in Malaysia. Recovery aims first at REE and may later include phosphate, Nb, Ta and Y (3.1%). At present, the main product is NdPr.

    Within a volcano-sedimentary greenstone belt of the Yilgarn craton, a circular aeromagnetic and high-density anomaly led to discovery of Mt. Weld (Pirajno et al. 2017). Lynas Corporation acquired the property in 2011 and developed the mine. Unaltered soevite carbonatite comprises calcite, dolomite, apatite, magnetite and pyrochlore. Its globular textures indicate an origin as fluidized vent material (Pirajno et al. 2017). Leaching of calcite and supergene alteration produced the 10-90 m thick mineralized regolith.

    Mt_Weld
    The photograph shows the main pit at Mt. Weld. Light and dark rocks in the lower part differ by Fe-oxide contents. Higher Fe correlates with high REE grade. The horizontally bedded cover are Cretaceous lake and swamp sediments. Credit Lynas Corporation 2018.

    Lynas Corp. ist listed on the Australian stock exchange (ASX code LYC). After ups and downs its share value was at 2 A$ on July 18, 2018 (https://www.asx.com.au/asx/). On the company website (https://www.lynascorp.com/), there is ample information on financial matter, mining and reserves/resources, but for a professional, little geological detail.

    Pirajno, F., Gonzalez-Alvarez, I., Border, A. & Porter, T.M. (2017) Mt. Weld and Gifford Creek rare elements carbonatites. Pp 163-166 in Australian Ore Deposits (ed G.N. Phillips), Australasian Institute of Mining and Metallurgy.

    JORC (2012) Australasian Code for Reporting of Exploration Results, Mineral Resources and Ore Reserves (The JORC Code). Available from: (The Joint Ore Reserves Committee of The Australasian Institute of Mining and Metallurgy, Australian Institute of Geoscientists and Minerals Council of Australia).


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    Is lateral secretion an ore-forming process? (June 11, 2018)

    What is lateral secretion? -- According to the American Geological Institute (AGI) Glossary of Geology (Neuendorf et al. 2006), lateral secretion is a theory of ore genesis first formulated in the 18th century and passing in and out of use since. It postulates the formation of ore deposits by the leaching of adjacent wall rock. Then, the authors describe the current use as convective fluids driven by cooling plutons.

    In my Economic Geology book (EG, Pohl 2011) I did not follow the remainder of the AGI definition because linguistically, secretion is the act or product of secreting (eg a substance produced by a gland), or mineral matter formed by inward growth in a cavity (The Chambers Dictionary 10th Edition 2006).

    The genetic model that I sketched in 2011 (EG: page 127) consisted of metamorphic fluids segregated from a rock during metamorphic dehydration, sucked into a fissure, not convecting and, opposed to the metamorphogenic-hydrothermal model, not moving over great distances. In 2011, I doubted that lateral secretion can form ore (a body of ore or minerals that is of economic interest).

    But I erred. Meanwhile, as a co-author in Thomas et al. (2018) I published a case of lateral secretion where a handful of gemstones may have the same value as a million tonnes of metal ore.

    Read the updated version of my 2011 text on lateral secretion:

    Lateral secretion is different from metamorphogenic ore formation. It is best exemplified by the common and ubiquitous generation of quartz and carbonate veinlets from host rocks at low metamorphic grades and of pegmatitic mobilizates at high grades. This interpretation is confirmed by the clear correlation between the paragenesis of the secretion veins (also called segregation veins) and the chemistry of the enclosing rocks: Quartz mobilizates, for example, occur in siliceous metasediments, whereas calcite veinlets form in limestone marble and in basic metavolcanic rocks. In the latter case, veinlets include epidote, chlorite and sulfides. Lateral secretion veins are mostly tensile structures that originate in syn- to late-metamorphic stages. Lateral secretion should result in a balanced mass exchange between host rocks and veins. Mobilized elements in the first decrease in concentration with proximity to the veins. Because of the chemical equilibrium between fluids and rocks, lateral secretion imprints no hydrothermal alteration on host rocks and stable isotopes reflect an equilibrium: Fluids and dissolved matter, or liquids are of local derivation. A transient pressure gradient induces movement of fluids or liquids that are initially dispersed in the rocks, to the opening fissure. Fluids/liquids move along grain boundaries, microcracks or by diffusion. This system is spatially limited and essentially closed. In its pure form there is no inflow from beyond its boundary and little outflow. In tectonically quiescent times, temperature and pressure in the fissure and the country rocks are equal, but pressure drops where extensional strain creates a fissure (see Figure).

    Secretion
    Principles of lateral secretion (adapted from Pohl 2011). Changes in the orogenic stress field lead to opening of a fissure. The resulting pressure gradient (P fissure < P lithostatic = P fluid) enforces flow of metamorphic fluids or liquids into the fissure where minerals precipitate. The system is closed within narrow limits (Halo of suction). The fluids are dilute solutions (or partial melts) of the surrounding host rock.

    Background fluid pressure is lithostatic. Because of the limitations concerning the mass of participating fluids and dissolved matter, a lateral secretion system is not expected to form economic metallic or mineral deposits (apart from pockets of gems or rare mineral specimen). Lateral secretion veinlets demonstrate the possibility of a temporary retention of metamorphic fluids or liquids in a dehydrating hot rock body.

    A case that fits lateral secretion resulting in gold ore formation was described by Tomkins (2007): Metamorphism often causes a loss of sulfur and formation of pyrrhotite or magnetite from pyrite (desulfidation). This sulfur is dissolved in prograde dehydration fluids (e.g. water from breakdown of chlorite), at low T in the form of H2S and S3- at high T. By forming thiocomplexes, these fluids may mobilize metals such as gold and silver that were hosted in original pyrite/arsenopyrite. Precipitation commonly takes place in the immediate wall rocks, where the fluids encounter minerals with reduced iron. In this way, metamorphic lateral secretion type ore of pyrrhotite, gold and silver can be formed.

    References

    Neuendorf, K.K.E., Mehl, J.P. & Jackson, J.A. (eds) (2005) Glossary of Geology. 5th edn. 779 pp. American Geological Institute.

    Pohl, W.L. (2011) Economic Geology, Principles and Practice: Metals, Minerals, Coal and Hydrocarbons. An Introduction to Formation and Sustainable Exploitation of Mineral Deposits. 663 pp. Wiley Oxford.

    Thomas, R., Rericha A., Pohl, W.L., Davidson, P. (2018) Genetic significance of the 867 cm-1 out-of-plane Raman mode in graphite associated with V-bearing green grossular. Mineralogy and Petrology 112 (5), 633-645. https://doi.org/10.1007/s00710-018-0563-1.

    Tomkins, A.G. (2007) Three mechanisms of ore re-mobilisation during amphibolite facies metamorphism at the Montauban Zn-Pb-Au-Ag deposit. Miner. Deposita 42, 627-637.


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    The Nobel Brothers, Caucasian-Caspian Oil and the Maikop Source Rocks (May 18, 2018)

    The Caucasus-Caspian region was the site of the first major oil rush outside of the United States after in 1870, oil had been found near Titusville, Pennsylvania. When in the same year the Russian empire relinquished the oil monopoly, an explosion of entrepreneurship was released (Yergin 2009). Three years later, Robert Nobel, the oldest of the three famous brothers, visited Baku, at that time a small trading town in Russia, with the intention to buy walnut wood for army rifle stocks. He realized at once the business opportunity, bought petroleum wells and a distillery instead of wood, and launched a business that was soon a highly integrated oil combine closely competing with Rockefeller's American enterprise. Ludwig Nobel became the Oil King of Baku, brother Alfred (the founder of the Nobel Price) helped with financing. In the 19th century, oil drilling was in its infancy and scientific understanding was quite limited, but Ludwig employed the first professional petroleum geologist ever.

    In our days, petroleum systems are well understood and for conventional deposits, the source - migration - trap scheme is applied. Because unconventional oil and gas deposits, in which source and deposit are one, are economically very attractive, source rocks are of high interest.

    For several years already, a group led by Prof. Sachsenhofer of Leoben University, Austria, investigates source rocks of the Tertiary epicontinental Paratethys Sea that evolved in the foreland of the Alpine-Caucasus mountain chain. Frequent stages of isolation from global oceans caused dysoxic and anoxic conditions in sub-basins of the Paratethys. This bequeathed organic matter-rich sediments that became source rocks for numerous oil fields.

    The Maikop Group, developed in the Caucasus region, is considered to be one of the profuse source rocks of the eastern Paratethys, possibly charging Ludwig Nobel's oil fields. Along Belaya River in southern Russia, the Sachsenhofer group sampled a section of about 10 km length covering the total thickness of the Maikop Group (600 m) with ~200 samples (Sachsenhofer et al. 2017). In their paper, they provide a wealth of detailed data, such as lithology, paleontology, TOC, S, and Rock-Eval characteristics (pyrolysis data such as S1, S2, Tmax, and HI, the hydrogen index). In this region, the Maikop is immature; meaning that its kerogen with an average vitrinite reflectance of 0.30% Rr has not reached the oil producing stage. Along the Belaya River outcrops of the Maikop, most samples display the character of source rock but only part of the kerogen is marine and oil prone. TOC contents range from less than 1 to greater than 3 wt. %. Average HI is rather low (<300 mg HC/g TOC) as is Rock-Eval HC yield (Sachsenhofer et al. 2017).

    Belaya
    Sampling oil shale along the Belaya River, north of the Caucasus Mountains. Courtesy R.F. Sachsenhofer, Mining University Leoben.

    In the photograph, a prominent white bed is seen embedded within brown organic-rich clay. This is the Polbian (Ostracoda) Bed, a marker horizon of less than 1 m thickness, characterized by brackish-water mollusks, nannoplankton, diatoms, ostracodes, and dinocysts. Maximum TOC (3.5 wt. %) and HI (420 mg HC/g TOC) were measured approximately 7.5 m above the Polbian Bed in calcareous clay. The true HI of this interval is as high as 575 mg HC/g TOC indicating the presence of kerogen type II. The Polbian is a limestone nearly free of organic matter. It is interpreted to reflect a Paratethys-wide significant decrease in salinity resulting from a temporary isolation from the world oceans (Sachsenhofer et al. 2017).

    Allow me final note - 600 m of siliceous oil shale with a huge energy content, although of low grade, of near surface horizontal disposition is a great potential future asset. In view of the rich oil fields from the Black Sea to the Caspian Sea, with the city of Maikop one of the centres, the authors (Sachsenhofer et al. 2017) suggest that other source rocks such as an Eocene horizon might have charged the oil fields that were hitherto attributed to the Maikop source rocks.

    References

    Sachsenhofer, R.F., Popov, S.V., Akhmetiev, M.A., et al. (2017) The type section of the Maikop Group (Oligocene-lower Miocene) at the Belaya River (North Caucasus): Depositional environment and hydrocarbon potential. AAPG Bulletin 101, 289-319.

    Yergin, D. (2009) The Prize. 908 pp. Simon & Schuster, Free Press.


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    Less than Two Weeks to go: Submit your Abstract for the 1st Conference of the Arabian Journal of Geosciences! Extended to May 15 (May 6, 2018)

    The 1st CAJG conference will take place from November 12-15, 2018 at Hammamet, Tunisia. Hosts are Abdullah Al-Amri (Founder & Editor-in-Chief of the Arabian Journal of Geosciences) and Nabil Khelifi (Senior Editor, MENA Program, Springer, Germany).

    Here is the link/URL to the conference website:

    http://www.cajg.org/index.php?p=welcome

    .

    Deadline for submissions (15 May 2018)


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    Melt Inclusions and the Origin of Tsavorite: A Breakthrough! (March 17, 2018)

    For several years I have learnt to admire the work of Rainer Thomas who is one of the few scientists mastering the techniques of investigating melt inclusions (MI). Frozen melt inclusions are common in most igneous rocks. They are similar to fluid inclusions in their capability to preserve chemical and P/T data that allow genetic insights. Rainer's results in using MI in pegmatite formation research first inspired my interest (e.g. Thomas & Davidson 2016, and earlier work).

    Tsavorites are gem quality green grossularites and have always been explained to have crystallized from metamorphic fluids. Rainer's fascinating discovery concerns the existance and important role of a supercritical melt/fluid (SCMF) phase in pegmatite ore formation. This SCMF phase can contain widely varying percentages of volatiles and has strange properties, similar to but not identical to supercritical fluids.

    A couple of years ago, when I had a chance to visit one of the tsavorite mines in SE Kenya, where earlier I had done geological mapping (Pohl et al. 1979), I connected the two strings and decided to ask Rainer if he would cooperate in order to unravel the origin of these rare gemstones. In sections of the samples I brought from Scorpion mine, Rainer soon discovered numerous melt inclusions but also graphite that is at present one of his main research interests. The resulting paper by Thomas et al. (lately accepted for print by MINPET) puts the hard data on the table and provides our interpretations. For the tsavorites, just read the last sentences of the Abstract below.

    Tsavorite_Crystal
    Green grossularite garnet (about 25 mm across), idiomorphic, cataclastic; with a kelyphitic rim (5 mm) of bluish tanzanite (a V-zoisite), epidote, clinopyroxene, spinel, quartz and scapolite. Collected by WLP at Lualenyi Mine (Mgama Ridge).

    Citation and Abstract:

    Thomas, R., Rericha A., Pohl, W.L., Davidson, P. (2018) Genetic significance of the 867 cm-1 out-of-plane Raman mode in graphite associated with V-bearing green grossular. Mineralogy and Petrology 112 (5), 633-645. https://doi.org/10.1007/s00710-018-0563-1

    SE Kenya is the world's largest producer of green vanadium grossular gemstones (tsavorite). Samples from one of the mines near Mwatate, and of occurrences in Tanzania yielded remarkable new insights into the genesis of tsavorite. Graphite is intimately associated with V-grossular and is one of the keys to understanding its origin. In the course of this study we found five different types of graphite. Surprisingly,in one graphite type the "Raman-forbidden" and IR-active 867 cm-1 band was observed. In this communication, we attempt to find an explanation for this unusual phenomenon. Additionally, our observations also address some of the issues pertaining to the origin of the green grossular-dominated rocks (grossularites), as well as the gem quality tsavorite crystals, since we propose that the anomalous spectroscopic behavior of the graphite is related to the unusual conditions during crystallization of both the grossular and graphite from a near-supercritical volatile- and sulfur-rich silicate melt. The massive green vanadium grossular contains abundant unequivocal crystallized melt inclusions, while the transparent gem quality grossular (tsavorite) displays only fluid inclusions. On the basis of inclusion studies we suggest that anatectic melts originated in the peculiar evaporitic host lithology of the tsavorite deposits. Near peak metamorphic temperatures (~700 degrees C) these liquids occurred as a supercritical volatile-rich "fluid/melt phase" characterized by complete miscibility between H2O and silicate liquid. Relatively dry liquid batches precipitated nontransparent green grossular, whereas wet batches segregated fluids that formed transparent tsavorite.

    References

    Pohl WL, Nauta WJ, Niedermayr G (1979) Geology of the Mwatate Quadrangle and the Vanadium Grossularite Deposits of the Area (with a Geological Map 1:50,000). Kenya Geol Survey Report No. 101, Nairobi. https://www.researchgate.net/profile/Walter_Pohl

    Thomas, R. & Davidson, P. (2016) Revisiting complete miscibility between silicate melts and hydrous fluids, and the extreme enrichment of some elements in the supercritical state: Consequences for the formation of pegmatites and ore deposits. Ore Geology Reviews 72, 1088-1101. doi: 10.1016/j.oregeorev.2015.10.004


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    Open access paper: Review of passive systems for acid mine drainage treatment (February 13, 2018)

    If you should be working in a mine that emits acid mine drainage, and you want to learn more about how to deal with that, this paper by Skousen et al. (2017) published in the journal Mine Water and the Environment is a great source of the basic science and its application.

    Read the Abstract:

    When appropriately designed and maintained, passive systems can provide long-term, efficient, and effective treatment for many acid mine drainage (AMD) sources. Passive AMD treatment relies on natural processes to neutralize acidity and to oxidize or reduce and precipitate metal contaminants. Passive treatment is most suitable for small to moderate AMD discharges of appropriate chemistry, but periodic inspection and maintenance plus eventual renovation are generally required. Passive treatment technologies can be separated into biological and geochemical types. Biological passive treatment technologies generally rely on bacterial activity, and may use organic matter to stimulate microbial sulfate reduction and to adsorb contaminants; constructed wetlands, vertical flow wetlands, and bioreactors are all examples. Geochemical systems place alkalinity-generating materials such as limestone in contact with AMD (direct treatment) or with fresh water up-gradient of the AMD. Most passive treatment systems employ multiple methods, often in series, to promote acid neutralization and oxidation and precipitation of the resulting metal flocs. Before selecting an appropriate treatment technology, the AMD conditions and chemistry must be characterized. Flow, acidity and alkalinity, metal, and dissolved oxygen concentrations are critical parameters. This paper reviews the current state of passive system technology development, provides results for various system types, and provides guidance for sizing and effective operation.

    AMD_polluted_river
    Famous Tinto River some kilometers downstream of the large brownfield Rio Tinto copper mining area in SW Spain. For the background, read my blog about RIO TINTO Brownfield Mines - Remediate or Extract Remaining Resources? (25 May 2016). The photo dates from the wet season, when the water is not red and the pH tends towards neutral. Riparian vegetation is healthy but the banks are marked by ochreous iron oxy-hydroxides such as hydronium jarosite (yellow) and goethite. Such rivers can be remediated by limestone sand treatment (Skousen et al. 2017).

    Keywords (my choice): Anoxic limestone drains; Bioreactors; Design and construction; How do they work; Limestone leach beds; Limestone sand treatment for whole watersheds; Low-pH Fe oxidation channels; Open limestone channels; Wetlands.

    References

    Skousen, J., Zipper, C. E., Rose, A. et al. (2017) Review of passive systems for acid mine drainage treatment. Mine Water Environ (2017) 36:133-153. Open access. https://link.springer.com/article/10.1007/s10230-016-0417-1


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    Hot early Earth (4500 to ~2500 Ma) - Lid Tectonics and Metallogeny (January 05, 2018)

    The Earth's mantle is the ultimate source of many ore forming systems. According to present-day understanding, the mantle formed during accretion and melting of meteoritic matter, although perhaps the meteorites in our collection are not particularly good examples of Earth's building blocks (Carlson 2017). The magma ocean stage facilitated differentiation of the metallic core that collected the siderophile elements (Table 1.1) producing the primitive mantle composition (Allegre 2008). For the following ~2 billion years, the early Earth was covered by a thin, stagnant lithosphere with a komatiite-basalt crust (the lid) that enclosed the planet interior. Episodically, heat accumulation was released by mantle overturn events that produced giant ourpourings and the first patches of continental crust (lid tectonics, Bedard 2018).

    Archaean_Earth_Dynamics
    Scaled cartoon illustrating an Archaean stagnant-lid crust and mantle overturn system. (A) Between overturn events (sometime between 3.9 and 2.7 Ga), Earth's surface is a mosaic of basalt - komatiite shield volcanos (green). (B) During a mantle overturn event, thermally buoyant lower mantle ascends as large plume-like structures. Courtesy Jean H. Bedard (2018).

    The Earth appears to be unique among planets so far known in space by an evolution towards plate tectonics and life. Early Earth, however, resembled other rocky planets and moons by the formation of a stagnant shell (a lid) enclosing a convecting hot mantle. Episodic overheating resulted in cracking of the lid, mantle overturn, fissure eruption of basalts and komatiites, and differentiation of felsic melts that formed first embryonic patches of typical Archaean crust. Orogeny was driven by imbrication or subcretion ahead of drifting microcontinents (Bedard 2018). The transition from lid tectonics to plate tectonics was local and gradual until 2.5 Ga, when plate tectonics took over.

    Bedard (2018) proposes a model of an Archaean stagnant-lid crust and mantle overturn system including lid tectonics with some brief references concerning metallogeny. In my words: Within the basalt-komatiite units, thick BIF (Algoma type banded iron formations) and chert sequences are intercalated. Komatiite ores are rivers of nickel sulfide. Archaean volcanogenic polymetallic massive base metal-sulfide (VMS) deposits may have formed from fluids mobilized by reheating of the fissured porous submarine volcanic pile, caused by new magma pulses. The deep sections of imbricated foreland terranes are the source of gold-carrying metamorphic fluids, resulting in orogenic Au deposits.

    Gold quartz-vein ore at Kalgoorlie (Western Australia) is dated at 2651 +/- 9 Ma. The Golden Mile (1700 t Au) and many other orogenic-class deposits in the region are spatially associated with stocks and dykes of high-Mg calc-alkaline monzodiorite-tonalite porphyry, part of a late-orogenic (2665-2645 Ma) mantle-derived magnetite-series suite of adakitic affinity (Mueller et al. 2016). The abundance of Au-Ag telluride ore (15-20 % of total gold) in the Golden Mile has prompted comparison to the intrusion-related gold telluride deposits common in Cenozoic magmatic arcs. Is the Golden Mile a suprasubduction deposit? Should it be separated from the orogenic-type group?

    Lid tectonics are not consolidated and much work remains to be done (Bedard 2018). Studies of Archaean metallogeny (e.g. Phillips 2017) are yet to include the new concepts.

    References

    Bedard, J.H. (2018) Stagnant lids and mantle overturns: implications for Archaean tectonics, magma genesis, crustal growth, mantle evolution, and the start of plate tectonics. Geoscience Frontiers 9, 19-49. https://doi.org/10.1016/j.gsf.2017.01.005 Open access. Open Access funded by China University of Geosciences (Beijing)

    Mueller, A.G., Hagemann, St.G. & McNaughton, N.J. (2016) NeoArchean orogenic, magmatic and hydrothermal events in the Kalgoorlie-Kambalda area, Western Australia: constraints on gold mineralization in the Boulder Lefroy-Golden Mile fault system. Miner. Deposita 10.1007/s00126-016-0665-9

    Phillips, N. (ed) (2017) Australian ore deposits. Monograph 32, 6th ed. 879 pp. Australasian Institute of Mining and Metallurgy.


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    Subsalt Oil in the Atlantic - the New Eldorado? (December 12, 2017)

    In the last few years, subsalt offshore exploration in the Southern Atlantic opened up new giant hydrocarbon provinces, both on the African and the South American side. For decades, the thick Aptian (ca. 100 Ma) salt along both passive margins had been the impenetrable floor for oil exploration; diapirs and salt pillows provided numerous traps in the postsalt sediments, commonly Upper Cretaceous carbonates and Cenozoic clastics. In Brazil, for example, shallow fields in the offshore basins of Campos, Santos and Espirito Santo had been and are still exploited. In 2005, exploring the subsalt potential started with a first exploration well targeting presalt reservoirs in deep waters. Since then, more than 25 discoveries have been reported in the presalt column with a total recoverable resource of >30 billion barrels (bbl). Current subsalt production is at ~926,000 bl/d.

    One remarkable discovery (2012) is the Pao de Acucar accumulation in the Campos Basin (Vieira de Luca et al. 2017). The Campos Basin originated by off-axis rifting in the Jurassic. Thinned metamorphic basement is overlain by tholeiitic volcanic rocks such as subaqueous pillow lavas and laminated volcanoclastics. Horsts and grabens controlled the subsequent sedimentation of shallow microbial carbonates, fine grained siliciclastics and chemical sediments deposited in an alkaline/saline lake that evolved during the thermal sag phase of the basin. On top and laterally of this shallow lake suite, a ca. 100 m thick layer of calcic-dolomitic laminated organic-rich shales is thought to represent a deep lacustrine facies that sourced the hydrocarbons. The terrestrial sediments are overlain and sealed by the marine evaporites of the Aptian salt.

    Sugarloaf
    Photograph showing the Bay of Botafogo and the Pao de Acucar, which is the Portuguese name for Sugarloaf Mountain at Rio de Janeiro, Brazil. Credit to Wikimedia Commons: Courtesy Halley Pacheco de Oliveira.

    At Pao de Acucar, innovative interpretation of old and new seismic data showed a broad antiformal hill that was chosen as the target for a first well. The well revealed three microbial carbonatic sequences on top of a volcano-tectonic high (a carbonate platform according to the authors), that interfinger downslope with the shales of the Upper A source rock unit. The subsalt column is peculiar because of pervasive hydrothermal brecciation and alteration, mainly silicification, that induced favourable reservoir properties including ~13 % porosity. Hydrocarbon generation post-dates the hydrothermal event. The hydrocarbon reservoir comprises fractured basalt and silicified vuggy carbonates that contain a productive hydrocarbon column of nearly 500 m, with valuable light oil (42 to 46 degrees API), condensate and gas. The source rock has total organic carbon (TOC) varying from 2 to 6%. With values of up to 900 mg HC/g Corg the hydrogen index (HI) indicates type I algal kerogen. Resources are estimated at 700 million bl of light oil and 3 Tcf3 of gas (Vieira de Luca et al. 2017).

    Pao de Acucar in the Campos Basin is an impressive subsalt discovery, in ultradeep waters offshore Brazil at depths ranging from 2500 to 2900 m. It is peculiar because the reservoir pore space originated by hydrothermal replacement of carbonates by silica. The field's feasibility is not yet established and the challenges to overcome are considerable, concerning geological, technical and financial issues (Vieira de Luca et al. 2017). At present, the competition with unconventional oil in the USA seems to be in favour of the latter, but this may change. Obstacles will be resolved. I believe that we are observers of the birth of a new Eldorado of black gold.

    Reference

    Vieira de Luca, P. H., Matias, H., Carballo, J., Algibez Alonso, J. L., Tritlla, J., Esteban, M. et al. (2017) Breaking barriers and paradigms in presalt exploration: The Pao de Acucar discovery (offshore Brazil). In R. K. Merrill & C. A. Sternbach (eds), Giant fields of the decade 2000-2010. AAPG Memoir 113, 177-194.


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    Australian Ore Deposits - Monumental! (November 17, 2017)

    Would you know a book that describes the ore deposits of a whole continent? A book that provides overview papers summarising regional geology and mineralisation for the different geological provinces and hundreds of descriptions of existing mines; articles arranged according to major geological provinces; papers being descriptive and intended to provide long-lasting data and information including geochemical and geophysical aspects; containing informative commodity overviews (W.A. Ni and Fe, Critical Metals, rare element pegmatites, Au, heavy mineral sand deposits in Australia, and major mining districts of (inter)national significance (e.g. Greenbushes Sn-Ta-Li, Mt. Weld REE, Golden Mile Au, Boddington-Wandoo Au, Mt. Tom Price Fe, channel iron deposits, Mt. Isa Cu-Pb-Zn-Ag and numerous others). For detailed Content, please refer to the URL provided below.

    Here is one of these extremely rare species, just published:


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    Diapirs
    Phillips, N. (ed) (2017) Australian ore deposits. Monograph 32, 6th ed. 879 pp. Australasian Institute of Mining and Metallurgy. The book can be bought as a hard copy, or in CD or USB format. Non-members of AusIMM are charged 190-160 A$, students 80 A$. URL http://www.ausimm.com.au/publications/publication.aspx?ID=17223

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    My interest in Kiruna-type iron oxide-apatite (IOA) and related iron oxide-copper-gold (U-REE) (IOCG) ore deposits (see my blog News El Laco Iron Ore: Conflicting Genetic Models /August 8, 2017) made me look up first the article on the giant Olympic Dam iron oxide Cu-U-Au-Ag deposit by Ehrig et al. (2017).

    You do know, of course, that Olympic Dam is the type deposit of the iron oxide-copper-gold (IOCG) clan which attribution was subsequently given to numerous deposits globally? I was curious to read the update and summary observations on the name-sake deposit.

    After introducing the history of discovery and development, Ehrig et al. (2017) provide the latest reserve and resource figures for the deposit: Total resource (2016) is 10,000 Mt at 0,77 % Cu, 250 ppm U3O8, 0.32 g/t Au, and 1 g/t Ag. Proven reserves amount to 150 Mt @ 2% Cu, 620 ppm U3O8, 0.63 g/t Au and 5 g/t Ag. This is followed by summaries of previous work, regional setting, local geology and alteration. The main alteration minerals are hematite, magnetite, muscovite and quartz. Details on alteration and mineralisation mineralogy and distribution are provided and illustrated. U-Pb ages of hydrothermal uraninite and hematite are within error equal to magmatic zircon of the Roxby Downs granite establishing (my words) a strong parental relation.

    I wonder, how many deposits of the IOCG clan resemble Olympic Dam by more properties than the paragenesis of magmatic-hydrothermal hematite and sulfides?

    Reference

    Ehrig, K., Kamenetsky, V.S., McPhie, J. et al. (2017) Olympic Dam iron oxide Cu-U-Au-Ag deposit. Pp 601-609 in Australian ore deposits (ed G.N. Phillips), Australasian Institute of Mining and Metallurgy.


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    Run-away climate? Is Limestone the Salvation? (October 26, 2017)

    Already today, limestone is an eminently essential material in environmental engineering. A new role is envisaged for controlling climate warming. You know that apart from reducing emissions, various techniques of solar geoengineering, also called climate intervention or climate engineering are considered.

    The argument is that injecting aerosols or aerosol precursors (such as CaCO3 or SO2) into the stratosphere or near the base of clouds can shield the Earth�s surface from incoming radiation and thus provide a negative forcing of the temperature and offset the positive forcing due to increased greenhouse gas concentrations. Volcanic eruptions provide natural examples of this effect. In June 1991, Mt. Pinatubo blew ~10 Mt of sulfur into the stratosphere and caused detectable cooling without disruption of the climate system. Another method might be fertilizing the high oceans with iron in order to amplify biomass production enhancing carbon storage by burial of organic matter in ocean floor sediments. Such actions could slow warming and provide time for the huge investments needed to reduce human CO2 emissions and to mitigate consequences of climate change.

    The recent proposal by a group of scientists from Havard University is a great improvement on earlier thoughts. They demonstrate that calcite aerosol geoengineering may cool the planet while simultaneously repairing the ozone layer (Keith et al. 2016). For more detail, read their Abstract:

    Injecting sulfate aerosol into the stratosphere, the most frequently analyzed proposal for solar geoengineering, may reduce some climate risks, but it would also entail new risks, including ozone loss and heating of the lower tropical stratosphere, which, in turn, would increase water vapor concentration causing additional ozone loss and surface warming. We propose a method for stratospheric aerosol climate modification that uses a solid aerosol composed of alkaline metal salts that will convert hydrogen halides and nitric and sulfuric acids into stable salts to enable stratospheric geoengineering while reducing or reversing ozone depletion. Rather than minimizing reactive effects by reducing surface area using high refractive index materials, this method tailors the chemical reactivity. Specifically, we calculate that injection of calcite (CaCO3) aerosol particles might reduce net radiative forcing while simultaneously increasing column ozone toward its preanthropogenic baseline. A radiative forcing of −1 W⋅m−2, for example, might be achieved with a simultaneous 3.8% increase in column ozone using 2.1 Tg⋅y−1 of 275-nm radius calcite aerosol. Moreover, the radiative heating of the lower stratosphere would be roughly 10-fold less than if that same radiative forcing had been produced using sulfate aerosol. Although solar geoengineering cannot substitute for emissions cuts, it may supplement them by reducing some of the risks of climate change. Further research on this and similar methods could lead to reductions in risks and improved efficacy of solar geoengineering methods.

    Diapirs
    Calcite in the air?

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    Is this not a wonderful innovation? The paper is Open Access classified, so you can and should read it in full length. The authors calculate for 1 Mt (million tonnes) of calcite per year; compared to a global production of ca. 300 Mt of lime and Ca-hydrate per year, the resources of calcite (limestone) should easily support such a program.


    Reference


    Keith, D.W., Weisenstein, D.K., Dykema, J.A. & Keutsch, N. (2016) Stratospheric solar geoengineering without ozone loss. Proceedings of the National Academy of Sciences (PNAS) 113, 14910�14914. Open Access. http://www.pnas.org/content/113/52/14910.abstract.html?etoc

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    Innovation in Digital 3D Surveying and Geological Mapping of Steep Terrain (September 6, 2017)

    A provocative paper in the last Issue (9/2017) of GSA Today (Pavlis & Mason 2017; see below) declares the dawn of a new mapping age, using available and yet-to-be-developed equipment and software, halting the decline of mapping capability.

    Today, cliffs, rock walls and steep opencast slopes are often surveyed with ground-based LIDAR (light detection and ranging) scanners. Orthophoto-like images are routinely made for surveying pits and the mine near-field with unmanned aerial vehicles (UAVs or �drones�).

    Pavlis & Mason (2017) describe how in steep mountains, canyons (or mines), Structure from Motion (SfM or multi-view) stereo photogrammetry in conjunction with UAVs, allows construction of inexpensive, high-resolution, photorealistic 3D terrain models. Using appropriate software, these models support the next generation of true 3D geological mapping.

    The authors present a case study with work flow applied to complexely folded basement in Surprise Canyon, California, USA. They have a number of proposals how to drive this evolution further, such as the development of a low-cost, lightweight drone that could become every geologist�s �field assistant�. Multi- and hyperspectral sensors for UAV will potentially lead to a �geologist�s ability to develop 3D lithological classification maps in the field - giving them live, multispectral eyes�. Not always is it clear for a quick reader, which part of the visions is already possible now, and what is expected for the future.

    Drone
    My personal field assistant drone surveying a rock fall

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    Let the authors speak for themselves:

    CONCLUSIONS Three-dimensional terrain models derived from SfM, particularly when augmented with aerial photography from UAS, provide an inexpensive base for the next generation of geologic mapping using a 3D interface. Visualization of these models frees geologists from the confines of flat maps and allows high-precision mapping of steep slopes and cliffs, which are virtually invisible in conventional maps. The ability to easily examine multiple view angles of Earth�s 3D surface outside the time limitations and logistical constraints of fieldwork is a cognitive breakthrough that frees field geology from the one-site�one-visit paradigm. Many geologists have lamented the decline of field geology, but the rise of these 3D technologies has a potential to revitalize field geology and launch a new generation of studies. Research is desperately needed, however, on ideal workflows that employ this technology across a range of applications and the range of field sites, and perhaps most importantly, how this technology can aid 3D learning rather than hinder it.


    References


    Pavlis, T.L. & Mason, K.A. (2017) The new world of 3D geologic mapping. GSA Today 27, no. 9, 4-10. DOI: 10.1130/GSATG313A.1

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    El Laco Iron Ore: Conflicting Genetic Models (August 8, 2017)

    No one working in economic geology can miss the observation that often, genetic interpretations are contradictory. Opposing hypotheses exist for decades, and new papers promoting one view soon provoke new arguments from the other side.

    Such a case is the origin of the Kiruna-type iron oxide-apatite (IOA) ore deposits: traditional genetic model of essentially orthomagmatic origin is opposed by recurring hydrothermal replacement hypotheses. The Kiruna district in Sweden is geologically ancient and complex. Maybe the youngest of the family can illuminate us, represented by iron ore on the Pliocene-Pleistocene El Laco stratovolcano of andesitic to dacitic composition in the High Andes of northern Chile?

    On the flanks of El Laco volcano (5325 m a.s.l.), there are seven large deposits of high-grade iron ore within an area of 30 km2, with total resources exceeding 1500 million tonnes. The ores are composed of magnetite (or martite), and minor amounts of hematite, anhydrite, apatite and pyroxene.

    Magnetite
    Black magnetite ore outcrop on the flank of El Laco volcano, Chile. Credits to Matthias Benz / Germany / www.world-of-crystals.com/

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    In the early 1960s the first published report on the El Laco iron ore described lava-like magnetite flows but later exploration work showed that beneath the hard surface, friable ore of pyroclastic appearance is predominant. Several papers published around the year 2000, however, proposed a hydrothermal replacement origin.

    In 2015-2017, four independent papers were published that substantiate an orthomagmatic-extrusive and pyroclastic formation of the El Laco ore. Tornos et al. (2016) confirm macroscopic observations that textures of massive ore are strikingly similar to those of vesicular low viscosity basalt and report O-isotopic data from El Laco suggesting that basalt-like iron oxide ore blankets are in fact solidified melts; plagioclase phenocrysts in andesite, for example, contain melt inclusions with two immiscible melts, one of silicates, the second rich in iron and with small tenors of Ca, Mg, Si, Ti, and P; this confirms the segregation of an ore melt. During quenching, the iron oxide melt released large volumes of super-hot volatiles (>900o C) and some hydrosaline melt. The latter caused magmatic-hydrothermal alkali-calcic alteration of the host andesite, which is similar to IOCG related alteration, providing the main argument for a possible hydrothermal replacement origin. HF-rich vapor produced a cap of acid-sulfate steam-heated alteration. In the latest of a long string of papers on El Laco and Kiruna, Nystr�m & Henriquez (2016) point out that the El Laco deposits are the best preserved examples of apatite iron ore of Kiruna type in the world. They illustrate convincingly features of ore such as vesicles and subvertical tubes that confirm widespread degassing during crystallization. Peculiar spherules of octahedral magnetite in the volcanic ash imply formation by rapid crystal growth in a gas plume during eruption of iron-oxide melt. Together, the new papers provide a vivid tableau of orthomagmatic-extrusive and pyroclastic formation of iron ore at El Laco.

    A third paper by Knipping et al. (2015) proposed a continuous transition from magmatic to hydrothermal processes and magnetite flotation as the best-fitting genetic model for Kiruna type iron oxide apatite (IOA) ore deposits. This model explains the random spatial distribution of Kiruna-type iron oxide-apatite (IOA) and of iron oxide-copper-gold (U-REE) (IOCG) ore deposits in the Cretaceous Chilean iron ore belt. The two deposit types may be formed from one magmatic system, at depth the IOA mineralisation, and nearer to the surface, the IOCG system. The erosion level determines what we see. In a forth paper, Barra et al. (2017) show a scheme of this arrangement in their Fig. 2. They report that Re-Os data of the Chilean deposits suggest a crustal source for both the IOA and IOCG mineralisation. Should we not have expected a mantle derivation?

    Is this the final word? - In spite of the admirable work presented above, it is not. Science continues to ask questions. Novel technologies will be developed and applied. Science and innovation are processes that will never end. Modified or radically new models will be built on the assembled knowledge and on new data. Let us always be prepared for change!


    References


    Barra, F., Reich, M., Selby, D. et al. (2017) Unraveling the origin of the Andean IOCG clan: A Re-Os isotope approach. Ore Geology Reviews 81, 62�78.

    Knipping, J.L., Bilenker, L.D., Simon, A.C. et al. (2015) Giant Kiruna-type deposits form by efficient flotation of magmatic magnetite suspensions. Geology 43, 591-594. http://geology.gsapubs.org/cgi/content/abstract/43/7/591?etoc

    Nystr�m, J.O., Fernando Henr�quez, F., Naranjo, J.A. & Naslund, H.R. (2016) Magnetite spherules in pyroclastic iron ore at El Laco, Chile. American Mineralogist 101, 587�595.

    Tornos, F., Velasco, F. & Hanchar, J.M. (2016) Iron-rich melts, magmatic magnetite, and superheated hydrothermal systems: The El Laco deposit, Chile. Geology 44, 427-430. DOI 10.1130/G37705.1

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    Sea-floor pockmark fields have widely varying origins (July 18, 2017)

    The search for petroleum and natural gas strives for a geological synthesis of basin evolution and related petroleum and gas systems in space and time (4D). A wide choice of tools and methods is used for attaining this goal. Because many oil and gas deposits are leaky, understanding hydrocarbon seeps and vents is always of high interest.

    Sea floor pockmarks are curious features that are commonly attributed to venting of methane. They are crater-like structures that originate by fast gas flow or eruptions. Diameters vary up to >1000 metres. Globally, pockmark fields comprise huge numbers of dispersed vents that occupy large areas of continental slopes and shelfs. As it happens, two papers describing and analysing the origin of pockmark fields have recently appeared, one concerning the Santos Basin offshore Brazil (de Mahiques et al. 2017; open access) and the other the northern North Sea offshore Norway (Mazzini et al. 2017). The interpretations of the mechanisms behind their formation and dynamics could not be more different. Please read on:

    The Santos Basin is part of the new giant hydrocarbon province offshore Brazil. A great role has Aptian (Early Cretaceous) salt as a seal and a structural agent. Diapirs intrude Mesozoic and Cenozoic sediments (Fig. 6). Some of them control hydrocarbon fluid flow from a sub-salt source to the ocean floor where the pockmarks have been found. The authors suggest that repeatedly, halokinesis enhanced the escape of fluid/gas from the subsurface to the water column. The main argument for this causal relation is the arrangement of the ca. 1000 pockmarks along diapir borders and related faults (de Mahiques et al. 2017).

    Diapirs
    Localisation of pockmarks along diapir borders and related faults (Fig. 6 of de Mahiques et al. 2017). Note older, buried pockmark layers marked (1). D are salt diapirs. Seismic reflection section courtesy de Mahiques et al. 2017.

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    The second paper introduces one of the World's largest pockmark fields located in the Troll region in the northern North Sea (Mazzini et al. 2017). Here, >7000 pockmarks are present in a ∼600 km2 area and many more likely occur over a 15,000 km2 region outside the study area. The vent distribution is irregular. No relation to the offshore gas field Troll ca. 80 km NW of Bergen, Norway, can be established. Troll contains giant gas reserves and considerable oil. The field lies on the eastern flank of the Jurassic Viking graben, in sandstones of the Middle to Late Jurassic Viking Group. Source rocks are Kimmeridgian Draupne shales in deeper parts of the graben in the West.

    Geochemical data from carbonate blocks collected from Troll pockmarks indicate a methanogenic origin linked to gas hydrate dissociation and past fluid venting at the seafloor. Carbonates collected from the vents gave an U�Th isochron age of 9.59�1.38 ka, i.e. the initial Holocene. The authors suggest that deglaciation could have triggered dissociation of gas hydrates formed during the last ice age in the region, as warming caused degassing of a methane hydrate layer below the seafloor. They stress the role of rapid warming following the Younger Dryas in affecting the marine gas hydrate reservoir (Mazzini et al. 2017).


    References


    de Mahiques, M.M., Schattner, U., Lazar, M. et al. (2017) An extensive pockmark field on the upper Atlantic margin of Southeast Brazil: spatial analysis and its relationship with salt diapirism. Heliyon 3 (2017) e00257. Open access. DOI 10.1016/j.heliyon.2017.e00257

    Mazzini, A., Svensen, H.H., Forsberg, C.F. et al. (2017) A climatic trigger for the giant Troll pockmark field in the northern North Sea. Earth and Planetary Science Letters 464, 24-34. http://dx.doi.org/10.1016/j.epsl.2017.02.014


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    Bauxite in China: The Product of a Mantle Plume? (June 15, 2017)

    Impossible! Or not? What would be your answer? Well, read the facts below, and let us come back to this hypothesis at the end:

    Most of China�s bauxite production is derived from karst deposits. One example of a bauxite mining province is western Guangxi in the South China Block, where resources comprise more than 500 Mt including Permian bauxite ore and its quaternary derivatives ( Liu et al. 2017). The bauxite province is adjacent to the mantle-plume-related Emeishan Large Igneous Province (LIP, formed at 262�257 Ma) that displays voluminous mafic lavas, mafic-ultramafic intrusions, rhyolites and A-type granites. At about the end of the Middle Permian, part of the shallow marine carbonate platform in the region was uplifted and karstified. On this karst surface, ash (?) and sediments derived from the Emeishan LIP were deposited. Bauxite formed during the Capitanian greenhouse event (ca. 265�254 Ma). Soon afterwards, the bauxite was buried underneath Late Permian and Triassic marine carbonate and clastic sediments. At the Pingguo bauxite deposit, cryptocrystalline or ooidal bauxite ore consists of diaspore, pyrite and anatase. Underneath the transgressive hanging wall limestone, kaolinite contents are elevated. The Emeishan source basalts bequeathed Fe and Mg as well as strontium, neodymium and lead isotopic characteristics. Pyrite sulfur isotopic compositions (−34.11 to −18.91�) reflect the microbial sulfate-reducing activity during diagenesis. Generally, many bauxite deposits demonstrate early oxidizing and acidic conditions followed by reducing and alkaline conditions. Evidence of microbial activity during formation and diagenesis at Pingguo is confirmed by images of fossilized microbes (Liu et al. 2017).

    Back to the Emeishan mantle plume: I suggest that indeed its activity caused (1) directly the emergence of the marine carbonate platform; (2) indirectly, by emission of CO2, the elevated temperatures and rainfall of the Capitanian greenhouse favouring karstification; and (3) the provision of basalt-derived sediments.

    The sober authors did not write down this speculation but provided the elements for the synthesis of this metallogenetic system. They deserve our praise!


    Reference


    Liu, Xuefei, Wang, Qingfei, Zhang, Qizuan et al. (2017) Genesis of the Permian karstic Pingguo bauxite deposit, western Guangxi, China. Miner. Deposita (as yet no volume no. attributed). DOI 10.1007/s00126-017-0723-y


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    Geofluids: Brief Review of an Excellent New Book (20 May, 2017)

    This is a wonderful book for all whose work concerns fluid and melt inclusions. Hurai et al. 2016 (citation below) cover the essential theory and the interpretation of inclusions analysis. For many themes, they provide worked examples of calculations (e.g. on page 183, Problem 6.2 Calculating oxygen fugacity from fluid composition). Explanations are patient, illuminating and readable. Numerous figures, mainly b/w line drawings help understanding. I believe that for users with a base in physical chemistry, the book should be suitable for self-learning. I am certain, that academic teachers and students will enjoy this book.

    Geofluids_Book
    Cover of Geofluids Book, Hurai et al. 2016

    Chapters of the book: General Characteristics � Phase Diagrams � Equations of State � Microthermometry � Interpretation of Microthermometric Data � Thermodynamics � Raman and Infrared Spectroscopic Anlysis - Miscellaneous Methods (including crsuh-leach analysis) � Stable Isotopes � Seven Appendices (Tables with equations of state, stable isotope fractionation equations, and Raman identification tables that aid in identification of inclusion solids).

    Ties to geological systems are frequently provided, e.g. hydrocarbons in fluid inclusions, the C-O isotope composition of carbonatite crystallization/devolatilization, graphite as a single-mineral geothermometer, the effect of fluid-rock interactions, or of hydrothermal alteration. Concluding the Stable Isotope Chapter, eight pages are devoted to the description of the metasomatic and vein siderite and magnesite mineralisation in the Western Carpathians (the Alpine belt in Slowakia). I happen to know the western extension of this province in Austria reasonably well (you may scan my list of publications). The authors use stable isotopes and fluid inclusions to weigh the evidence for competing genetic models: i) the older orogenic/metamorphic saline fluid hypothesis; and ii) the more recent evaporative brine convection hypothesis (Prochaska 2012). They conclude that high-pressured fluid inclusions combined with carbon and oxygen isotope data affirm the metamorphogenic model and contradict both the brine infiltration model and a genetic connection between siderite and magnesite (Hurai et al. 2016).

    This is a worthy successor to Roedder�s classic �Fluid inclusions� and an admirable summary of all the work done since. With a very different appoach, however, it is not an update of the other classic on geofluids: Fyfe et al. (1978) � Fluids in the Earth�s crust�.


    References


    Fyfe, W.S., Price, N.J. & Thompson, A.B. (1978) Fluids in the Earth�s crust. 383 pp. Elsevier.

    Hurai, V., Huraiov�, M., Slobodn�k, M. & Thomas, R. (2016) Geofluids - Developments in Microthermometry, Spectroscopy, Thermodynamics, and Stable Isotopes. 504 pp. Elsevier. https://www.elsevier.com/books/geofluids/hurai/978-0-12-803241-1

    Prochaska, W. (2012) Siderite and magnesite mineralisations in Paleozoic strata of the Eastern Alps (Austria). J. Alpine Geol. 54, 309-322.

    Roedder, E. (1984) Fluid inclusions. Reviews in Mineralogy 12, 644 pp. Mineral. Soc. America, Washington.


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    Mineral prospectivity modelling � its essence and limitations (20 April 2017)

    Modern mineral prospectivity modelling relies on a process-based, or �mineral systems� approach using Geographic Information Systems (GIS), which was developed in Australia during the last two decades (Hagemann et al. 2016a). Mineral system analysis (MSA) is a holistic genetic investigation that identifies all factors and processes that contribute to the origin and preservation of a mineral deposit, emulating (conventional) petroleum systems ( see Figure). For exploration, target models are based on the underlying mineralization processes and their mappable features.

    The critical mineralization processes acting together to form a hydrothermal ore deposit, for example, may include (a) the establishment of an energy gradient to drive the system; (b) the generation of hydrothermal fluids; (c) the extraction of metals and chemical ligands for metal complexation from suitable sources; (d) the transport of fluids and metals from source regions to traps (i.e. effective flow channels); (e) deposition of metals triggered by chemical and physical processes that affect fluids migrating through traps; and (f) the preservation of mineral deposits through time.

    Although processes cannot be directly observed or mapped, they can be translated into proxies such as wide alteration and thermal halos or syngenetic faults that may be recognizable (McCuaig et al. 2010). Modern systematic grid-sampled regional data including geochemistry and geophysics (magnetics, gravity, electromagnetic, seismic and future deep-sounding magnetotelluric tomographic surveys) and remote sensing are another key for this progress. Computational processing utilizes methods such as fuzzy logic, weights of evidence and artificial neural networks (Kreuzer et al. 2015). Output maps are decision-support tools for delineating, ranking, and prioritizing exploration targets. Overall, the systematic approach of MSA considerably improves predictive capabilities.

    In my opinion, Mineral System Analysis can be perceived as metallogeny in modern clothes. Metallogeny, founded by Louis de Launay (1913), is understood as the science of the origin and distribution of ore deposits in geological space and time. de Launay already suggested that this understanding would greatly assist in the search for ore. Find more information in my blog �What is metallogeny? Is it of any use? (10 February 2016)� at www.walter-pohl.com/News_Archive_2016.html.

    Oil_System
    Sketch of a simplified petroleum system showing source, migration and potential trap: A hydrocarbon-producing depression, or �kitchen�, displays a steeply dipping source rock layer that exhibits immature, mature and post-mature portions (modified from Hunt 1996; for details see Magoon & Dow 1994). Maturity is depicted by vitrinite reflectance in oil immersion (Ro). Oil generation is thought to start at RO = 0.62%, and gas with condensate below Ro = 1.0%. Hydrocarbons migrate upward and may collect in a structural trap. The effective drainage area is delimited by sufficient maturation and geological constraints.

    .

    Until now, however, reports of great new finds by application of mineral system analyses are rare apart from the publication of (yet untested) mineral potential sketch maps. A very instructive example is the comparison between mineral prospectivity modelling and the results of past exploration covering the important porphyry copper-gold province around Cadia and Northparkes mines in eastern Australia (Kreuzer et al. 2015). Another illuminating case is the companion paper on the �BIF-hosted iron mineral system� by Hagemann et al. (2016b).

    Apart from Australia, few countries have the will and the resources to launch an innovation project such as Deep Earth Imaging (CSIRO 2017). The full data set described above will rarely be available. Patchy coverage will be as common as for traditional exploration and assumptions will have to be made. Limited funds will always be a hindrance. Yet, the systematic approach is a great step forward.


    References


    CSIRO (2017) Deep Earth Imaging. Accessed 20 April 2017. URL https://www.csiro.au/en/Research/MRF/Areas/Resourceful-magazine/Issue-11/New-science-to-reduce-risk?utm_source=resourceful-2017-04&utm_medium=newsletter&utm_campaign=resourceful/

    Hagemann, S.G., Lisitsin, V.A. & Huston, D.L. (2016a) Mineral system analysis: Quo vadis? Ore Geol. Reviews 76, 504�522. http://dx.doi.org/10.1016/j.oregeorev.2015.12.012

    Hagemann, S.G., Angerer, T., Duuring, P. et al. (2016b) BIF-hosted iron mineral system: A review. Ore Geol. Reviews 76, 317�359. http://dx.doi.org/10.1016/j.oregeorev.2015.11.004

    Hunt, J.M. (1996) Petroleum geochemistry and geology. 743 pp. Freeman.

    Kreuzer, O.P., Miller, A.V.M., Peters, K.J. et al. (2015) Comparing prospectivity modelling results and past exploration data: A case study of porphyry copper-gold mineral systems in the Macquarie arc, Lachlan fold belt, New South Wales. Ore Geol. Reviews 71, 516�544. http://dx.doi.org/10.1016/j.oregeorev.2014.09.001

    Launay, L. de (1913) Trait� de M�tallog�nie. 3 Vols. Paris.

    Magoon, L.B. & Dow, W.G. (eds) (1994) The petroleum system from source to trap. AAPG Memoir 60, 1-655.

    McCuaig, T.C., Beresford, St. & Hronsky, J. (2010) Translating the mineral systems approach into an effective exploration targeting system. Ore Geol. Reviews 38, 128-138.

    Porwal, A.K. & Kreuzer, O.P. (2010) Introduction to the Special Issue: Mineral prospectivity analysis and quantitative resource estimation. Ore Geol. Reviews 38, 121-127.


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    Passing on a message from the Society of Economic Geologists (SEG) - Graduate Student Fellowship Program (14 April 2017)

    �I have come finally to the key message of this column. Students, wherever you are studying, wherever you are currently living, if you are considering the pursuit of graduate studies in economic geology, I strongly encourage you to apply to the SEG Graduate Student Fellowship Program or one of the other SEGF funds, such as the McKinstry Fund, if appropriate. Please visit the SEG Graduate Student Fellowship web page (www.segweb.org/GSF) to see the minimum requirements and the application process.�

    Stuart R McCracken (SEG Foundation President 2017)

    Published in SEG Newsletter 109, April 2017


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    Dolomite � Magnesite � Metasomatism: New Insights! (15 March 2017)

    Dolomite (also called dolostone) and magnesite rock of high purity and whiteness are highly valued in industrial applications. Usually, they are extracted from hard rock quarries, less often from underground mines. Typically, both form limited masses of 1-1000 Mt within marine limestones suites. Clearly, these bodies originated by chemical replacement of calcite (CaCO3) by dolomite [(CaMg(CO3)2 ] or magnesite (MgCO3), or in other terms, of partial or total replacement of Ca by Mg. The geological term for this replacement process is metasomatism. Sedimentary and diagenetic models of sparry magnesite metasomatism are closely related to concepts of dolomite formation.

    Most commonly, the details and variable possibilities of ore body scale metasomatism in geological nature are discussed in geochemical terms, employing various isotopic systems or trace element characteristics. I will not deny that geochemical methods allow surprising new approaches to genetic modelling. On the contrary, concerning dolomite and magnesite, I�ll just mention the novel use of Mg isotopes (Dong et al. 2016) or of clumped isotopes (Garcia del Real et al. 2016).

    Generally, pre-Cenozoic metasomatic bodies have experienced repeated passage of fluids and heat events, fudging genetic signals. Geologically young and well-preserved metasomatic deposits of dolomite, magnesite or siderite are rare, however. Therefore I found it diverting to read a case study of Miocene dolomite formation in the Gulf of Suez (Hollis et al. 2017). For gas and oil geology, dolomite often is a profuse reservoir, but in this case, we only learn a lot about fault-bound hydrothermal dolomite formation by deep convection of ordinary seawater. The authors stress that the characteristic pattern of (1) non-stratabound massive dolomite along faults and of (2) stratabound lateral tongues into host rock is not synchronous but that (2) clearly precedes (1). Formation temperatures were estimated at ∼40�70 �C (stratabound) and at ∼40�100 �C for the massive dolomite; certainly hot enough for the term �hydrothermal�. For students of �sparry� Veitsch-type magnesite, of hydrothermal dolomite, of metasomatic siderite, and of, among others, Irish-type base metals, this should be compulsory reading.

    By the way, a recent comprehensive paper on Hohentauern/Sunk, one of the typical Austrian sparry magnesite deposits, provides many modern data and confirms diagenetic replacement (Azim Zadeh et al. 2015).

    Fortunately, the Hollis et al. (2017) paper is Open Source classified. You may download and read it at your own leisure.

    Magnesite
    Pinolite-textured magnesite from Hohentauern-Sunk Mine, Austria. Note the crystal rosettes and general displacement of formerly dispersed impurities by crystals growing during diagenesis. Typical for stratiform/stratabound metasomatites, the fabric is weakly sedimentary features preserving and crystals display cloudy core�clear rimmed fabrics.

    References


    Azim Zadeh, A.M., Ebner, F. & S.-Y. Jiang (2015) Mineralogical, geochemical, fluid inclusion and isotope study of Hohentauern/Sunk sparry magnesite deposit (Eastern Alps/Austria): implications for a metasomatic genetic model. Miner. Petrol. 109, 555-575.

    Hollis, C., Bastesen, E., Boyce, A. et al. (2017) Fault-controlled dolomitization in a rift basin. Geology 45, 219-222.

    Gold Open Access: This paper is published under the terms of the CC-BY license. http://geology.gsapubs.org/cgi/content/abstract/45/3/219?etoc

    Garcia del Real, P., Maher, K., Kluge, T. et al. (2016) Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks. Geochim. Cosmochim. Acta 193, 222�250.

    Dong, A., Zhu, X.-K., Li, Sh.Zh., Kendall, B., Wang, Y., Gao, Zh. (2016) Genesis of a giant Paleoproterozoic magnesite deposit: Constraints from Mg isotopes. Precambrian Research 281, 673�683.


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    Arsenic: Well-drillers, be wary of water from reduced, grey sediments! (14 February 2017)

    Unrelated to mining, natural arsenic concentrations in aquifers and/or groundwater of lowland valleys throughout the world are a hidden hazard. In the Ganges delta, this caused humanity�s biggest mass poisoning. Earlier, millions of people in the region had relied on surface water. From 1980 to 1990 thousands of drinking water wells were drilled to provide �safe�, that is microbially clean water. Of these wells, nearly 50% had As of >10 micrograms/litre (WHO�s limit). Sadly, this was only recognized after numerous people had developed skin and internal disorders, including cancer. With 2-20 ppm, the As-concentrations in Ganges river sediments are quite ordinary. Most As is adsorbed in Fe-oxide particles. Spots of elevated dissolved arsenic occur in low-sulphate groundwater in the presence of reactive organic matter, which supports microbial reduction of iron oxides and oxy-hydroxides; this releases adsorbed arsenic (Bowell et al. 2014). Pumping increases recharge, which may trigger aquifer flushing and release of Fe(II) and As(III). Well-drillers should keep samples oft grey sediments and water, and ask for advice. Various removal technologies are available; if nothing else is possible, a cheap and efficient precaution is stirring the contaminated well water with iron oxy-hydroxide fines.

    Anthropogenic arsenic contamination is unfortunately not rare; mining, ore dressing, metallurgical processing (roasting plants and smelters) and general industry may be hotspots. I wonder how many of my readers work in mines that deal with elevated traces of arsenic, such as many of those extracting copper, gold, platinum and tin.

    If you are seeking an example for how to professionally investigate a potentially dangerous situation, I recommend a recent paper that describes work done for an ecological risk assessment (ERA). The site of the study is the Neoarchaean (2.61 Ga) Siilinj�rvi alkaline complex (16 x 1.5 km) in Eastern Finland that comprises carbonatite and syenite. Its core hosts an important deposit of apatite (an ore of phosphorus that is here the main mine product), glimmerite and calcite.

    At the Yara Siilinj�rvi industrial site, the apatite is treated with sulfuric acid to produce phosphorus fertilizers. The sulfuric acid in turn is made by roasting pyrite, of which some 860,000 tonnes per year are produced as a by-product of Cu and Zn at the nearby underground Pyh�salmi mine.

    Phosphate
    Photograph showing Yara Siilinj�rvi phosphate mine in Finland. Fertilizer plant in the foreground, calcined pyrite heaps in the background on the right. Courtesy Yara Suomi Oy.

    .

    The apatite mine, industrial plant as well as the calcined pyrite tailings storage heaps lie near a lake. Turunen et al. (2016) present an illuminating study of arsenic dispersion from the calcined pyrite tailings. The calcined pyrite consists of hematite; the tailings have a a high As content (500�654 mg kg-1) that is mobilized by seepage water, which is collected and reused as process water in the plant.

    The natural (geogenic) background As concentrations are very low so that hydraulically and geochemically, the gradient from the tailings to the environs and the lake is considerable. As expected, in spite of retaining measures, the migration of As by dust and water reaches the lake and is recorded in its sediments. Analytical results of many samples near the tailings exceeded the European Chemical Agency�s (ECHA) Predicted No Effect Concentrations (PNECs). For example, the As concentration in 64 % of the water samples exceeded the PNEC value for fresh water (0.5 l μg L-1). Dissolved arsenic and other potentially harmful metals brought in with the pyrite (Co, Cd, Cu and Ni) also pose a risk but the ubiquitous iron oxides retain and fix much of the metal load.

    The paper by Turunen et al. (2016) is a rich source on geochemical methods and technologies used. It is highly recommended. And it is freely downloadable under creative commons licence!


    References


    Bowell, R.J., Alpers, Ch.N., Jamieson, H.E., Nordstrom, D.K. & Majzlan, J. (2014) The environmental geochemistry of arsenic -- an overview. Rev. Mineralogy & Geochemistry 79, 1-16. DOI: 10.2138/rmg.2014.79.1

    European Chemicals Bureau (2003) Technical Guidance Document on Risk Assessment. European Communities. Available online at: https://echa.europa.eu/documents/

    Turunen, K., Backn�s, S., Neitola, R. & Pasanen, A. (2016) Factors controlling the migration of tailings-derived arsenic: A case study at the Yara Siilinj�rvi site. Mine Water Environ 35, 407-420. Keywords include Arsenic fractionation; Arsenic mobility; Soil chemistry; Water chemistry; Risk assessment. Free download under creative commons licence. http://link.springer.com/article/10.1007/s10230-016-0393-5


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    Diamond crystals forming in a metallic Fe-Ni-C-S melt � did humans re-invent nature�s secret? (17 January 2017)

    In my last blog (8 December 2016) I referred to the role of subduction in the process system of gem diamond formation (Stern et al. 2016). Soon after I had this published, another brilliant paper appeared, that reports on the crystallisation of natural diamond from a metallic Fe-Ni-C-S melt (Smith et al. 2016).

    Smith et al. (2016) investigated microinclusions in some of the famous great diamonds, such as the Cullinan from the Premier mine in South Africa, in rough weighing 3,106 carats, found in 1905. Based on common properties such as attribution to the low-N type II diamonds, large size and few but distinct microinclusions, the authors collected 53 similar diamonds. The microinclusions turned out to be magnetic solid phases crystallised from a metallic Fe-Ni-C-S liquid that was trapped during diamond growth. Like fluid or gas inclusions in minerals, silicate or metallic melt inclusions provide a wealth of genetic information. Other inclusions formed of silicates suggest that these diamonds formed in the mantle transition zone between 410 and 660 km depth. This is much deeper than the common gem diamonds that crystallised at the asthenosphere-lithosphere boundary (ALB) at 135-200 km. Several arguments support formation of this metallic melt within subducted eclogite. Light carbon isotopic compositions point to a crustal biogenic origin. The authors propose to call this specific group of type II diamonds CLIPPIR (Cullinan-like, inclusion-poor, pure, irregularly shaped, and resorbed).

    Synthesis of diamond has been first attempted >100 years ago. Industrial production started some 60 years later. Today, most synthetic diamond is made from graphite in a metallic melt by the High Pressure/High Temperature (HPHT) technology at T>1400oC and P>59 kbar.

    Industrial diamond is foremost an abrasive that is used for drilling, grinding, sawing and polishing. Useful properties apart from its hardness include toughness, resilience against aggressive chemicals and high-temperature stability. Applications are numerous, ranging from microsurgery to computer chip production, deep drilling for petroleum and cutting large monolithic dimension stones. Most of this market is served by synthetic monocrystalline and polycrystalline diamonds.

    Only about 1% of the steadily growing demand for industrial diamonds is satisfied by mining natural diamonds. In 2015, world mine production of industrial grades reached 54 Mcts. China alone produces >4000 Mct/yr (or 800 tonnes) of synthetic diamonds (USGS 2017). Even the production of synthetic gem diamonds is possible, at a fraction of the price of natural diamonds. Is branding the �true� stones a long-term solution?

    Cullinan_diamonds
    The Cullinan was the largest diamond ever discovered. It was cut by Assher�s in Amsterdam into 9 major gems and 96 small brilliants. The largest gem from the Cullinan is known as the Great Star of Africa, the largest cut diamond in the world. This and no. II are part of the British crown jewels. Here we see the stones no. IV and III. Source: Wikipedia public domain

    References


    Smith, E.M., Shirey, St.B., Nestola, F. et al. (2016) Large gem diamonds from metallic liquid in Earth's deep mantle. Science Vol. 354, Issue 6318, pp. 1403-1405. DOI: 10.1126/science.aal1303

    Stern, R.J., Leybourne, M.I. & Tatsuki Tsujimori (2016) Kimberlites and the start of plate tectonics. Geology 44, 799-802. http://geology.gsapubs.org/cgi/content/abstract/44/10/799?etoc


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